Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing-Shenfu Area     

TAO Chuanqi  WANG Yanbin  LI Yong  NI Xiaoming  GAO Xiangdong 《《地质学报》英文版》2020,94(2):399-408

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.  相似文献   

Early Jurassic palaeoenvironments in the Surat Basin,Australia – marine incursion into eastern Gondwana     

Andrew D. La Croix  Jianhua He  Valeria Bianchi  Jiahao Wang  Sebastian Gonzalez  Jim R. Undershultz 《Sedimentology》2020,67(1):457-485

Interpretations of palaeodepositional environments are important for reconstructing Earth history. Only a few maps showing the Jurassic depositional environments in eastern Australia currently exist. Consequently, a detailed understanding of the setting of Australia in Gondwana is lacking. Core, wireline logs, two-dimensional and three-dimensional seismic from the Precipice Sandstone and Evergreen Formation in the Surat Basin have been used to construct maps showing the evolution of depositional environments through the Early Jurassic. The results indicate the succession consists of three third-order sequences (Sequence 1 to Sequence 3) that were controlled by eustatic sea level. The lowstand systems tract in Sequence 1 comprises braidplain deposits, confined to a fairway that parallels the basin centre. The strata were initially deposited in two sub-basins, with rivers flowing in different orientations in each sub-basin. The transgressive systems tract of Sequence 1 to lowstand systems tract of Sequence 3 is dominated by fluvio–deltaic systems infilling a single merged basin centre. Finally, the transgressive and highstand systems tracts of Sequence 3 show nearshore environments depositing sediment into a shallow marine basin. In the youngest part of this interval, ironstone shoals are the most conspicuous facies, the thickness and number of which increase towards the north and east. This study interprets a corridor to the open ocean through the Clarence–Moreton Basin, or the Carpentaria and Papuan basins, evidence of which has been eroded. These results challenge a commonly held view that eastern Australia was not influenced by eustasy, and propose a more dynamic palaeogeographic setting comprising a mixture of fluvial, deltaic and shallow marine sedimentary environments. This work can be used to unravel the stratigraphic relationships between Mesozoic eastern Australian basins, or in other basins globally as an analogue for understanding the complex interplay of paralic depositional systems in data poor areas.  相似文献   

中国稀土元素地球化学背景与远景区优选     

王学求  周建  迟清华  王玮  张必敏  聂兰仕  刘东盛  徐善法  吴慧  高燕芳 《地球学报》2020,41(6):747-758

稀土元素是现代科技、新能源、特种制造的关键性材料, 以其不可替代性和稀缺性, 而备受关注, 很多国家将其列为关键资源或战略资源。地球化学是研究稀土分布和发现稀土矿床的有效方法。本文利用“化学地球”大科学计划获得的全国15个稀土元素地球化学基准数据以及“一带一路”的中蒙边境、中缅老越边境地区地球化学填图数据为基础, 阐述中国稀土地球化学背景和圈定远景区。获得全国岩石和汇水域沉积物15个稀土元素、轻稀土(ΣLREE)、重稀土(ΣHREE)和总稀土(ΣREE)背景值。全国岩石背景值分别为: ΣLREE 121 μg/g, ΣHREE 35.0 μg/g, ΣREE 157 μg/g, 轻重稀土比值为3.5。全国汇水域沉积物背景值分别为: ΣLREE 134.0 μg/g, ΣHREE 38.5 μg/g, 和ΣREE 173 μg/g, 轻重稀土比值为3.5。总体上汇水域沉积物与岩石一致, 但含量略高于岩石。全国共圈定稀土地球化学异常区35处, 其中有26处异常与已知稀土矿或稀土成矿带相吻合, 新发现稀土超富集中心的稀土异常9处, 分别位于内蒙白云鄂博以西的乌拉特中旗—乌拉特后旗、华南异常富集中心、松潘—甘孜—攀西地区、云南红河州—中越边境、三江南段—中缅边境、雅鲁藏布江东段、西藏札达地区、中塔边境、黔东正安—荔波地区。这些异常显示, 是具有寻找白云鄂博型、碱性岩型、离子吸附型、花岗伟晶岩型、磷块岩型和泥岩型稀土矿的有利地区。  相似文献   

青海共和盆地地热流体地球化学特征及热储水-岩相互作用过程     

马月花  唐保春  苏生云  张盛生  李成英 《地学前缘》2020,27(1):123-133

地热流体地球化学组成及其运移规律和成因机制研究对地热资源勘查和开发利用具有重要意义。当前,青海省地热资源开发利用程度低,更缺乏针对地热流体地球化学特征进行深入研究的系统性工作。青海共和盆地是青藏高原北缘的一个断陷盆地,盆地内地热资源丰富。本文以共和盆地及周围部分山区的地热系统为研究对象,基于系统地球化学采样和测试开展了地热流体地球化学组成及热储水-岩相互作用过程分析,认为:从共和下更新统热储、新近系热储到鄂拉山构造岩浆带再到瓦里贡山构造岩浆带,地热水中SiO₂含量依次升高,反映热储温度依次升高;上述地热地区热储中原生铝硅酸盐矿物的溶解和蚀变矿物的形成是控制地热水中阳离子含量的最重要的水文地球化学过程,而补给水下渗和地热水径流及升流过程中盐类矿物的溶滤则是水中阴离子(特别是 {\mathrm{SO}}_4^{2-}和Cl^-)的主要来源。  相似文献   

Mesozoic–Cenozoic stress field magnitude in Sichuan Basin,China and its adjacent areas and the implication on shale gas reservoir: Determination by acoustic emission in rocks     

《China Geology》2020,3(4):591-601

The Sichuan Basin is one of the vital basins in China, boasting abundant hydrocarbon reservoirs. To clarify the intensity of the tectonic stress field of different tectonic episodes since the Mesozoic and to identify the regional dynamic background of different tectonic movements in the Sichuan Basin and its adjacent areas, the characteristics of the acoustic emission in rocks in different strata of these areas were researched in this paper. Meanwhile, the tectonic stress magnitude in these areas since the Mesozoic was restored. The laws state that the tectonic stress varied with depth was revealed, followed by the discussion of the influence of structural stress intensity on structural patterns in different tectonic episodes. These were conducted based on the paleostress measurement by acoustic emission method and the inversion principle of the stress fields in ancient periods and the present, as well as previous research achievements. The results of this paper demonstrate that the third episode of Yanshanian Movement (Yanshanian III) had the maximum activity intensity and tremendously influenced the structural pattern in the study area. The maximum horizontal principal stress of Yanshanian III varied with depth as follows: 0.0168 x + 37.001 (MPa), R² = 0.8891. The regional structural fractures were mainly formed in Yanshanian III in Xujiahe Formation, west Sichuan Basin, of which the maximum paleoprincipal stress ranging from 85.1 MPa to 120.1 MPa. In addition, the law stating the present maximum horizontal principal stress varies with depth was determined to be 0.0159 x+10.221 (MPa), R²=0.7868 in Wuling Mountain area. Meanwhile, it was determined to be 0.0221 x+9.4733 (MPa), R²=0.9121 in the western part of Xuefeng Mountain area and 0.0174 x+10.247 (MPa), R²=0.8064 in the whole study area. These research results will not only provide data for the simulation of stress field, the evaluation of deformation degree, and the prediction of structural fractures, but also offer absolute geological scientific bases for the elevation of favorable shale gas preservation.  相似文献   

差分层析SAR技术研究现状分析     

张月  庞蕾  徐西桂  张天  张瑞菊 《测绘通报》2019,(1):5-12

差分层析SAR是在层析SAR基础上发展起来的一种四维信息反演技术。它不仅实现了对雷达目标的三维分辨能力，同时可以获取目标的形变速率信息，可实现对目标方位-距离-高度-时间四维成像，这对实现城市基础设施动态形变监测、古建筑风险评估、重要工程安全监测等应用具有重要实际意义和价值。本文基于差分层析SAR成像原理，分析了成像处理过程中存在的问题，总结了差分层析SAR成像算法研究现状和特点；最后列举了差分层析SAR技术的主要应用领域，并对其技术发展趋势进行了展望。  相似文献   

Paleogene evolution and demise of the proto‐Paratethys Sea in Central Asia (Tarim and Tajik basins): Role of intensified tectonic activity at ca. 41 Ma     

Mustafa Y. Kaya  Guillaume Dupont‐Nivet  Jean‐Noël Proust  Pierrick Roperch  Laurie Bougeois  Niels Meijer  Joost Frieling  Chiara Fioroni  Sevin zkan Alt&#x;ner  Ezgi Vardar  Natasha Barbolini  Marius Stoica  Jovid Aminov  Mehmut Mamtimin  Guo Zhaojie 《Basin Research》2019,31(3):461-486

The proto‐Paratethys Sea covered a vast area extending from the Mediterranean Tethys to the Tarim Basin in western China during Cretaceous and early Paleogene. Climate modelling and proxy studies suggest that Asian aridification has been governed by westerly moisture modulated by fluctuations of the proto‐Paratethys Sea. Transgressive and regressive episodes of the proto‐Paratethys Sea have been previously recognized but their timing, extent and depositional environments remain poorly constrained. This hampers understanding of their driving mechanisms (tectonic and/or eustatic) and their contribution to Asian aridification. Here, we present a new chronostratigraphic framework based on biostratigraphy and magnetostratigraphy as well as a detailed palaeoenvironmental analysis for the Paleogene proto‐Paratethys Sea incursions in the Tajik and Tarim basins. This enables us to identify the major drivers of marine fluctuations and their potential consequences on Asian aridification. A major regional restriction event, marked by the exceptionally thick (≤ 400 m) shelf evaporites is assigned a Danian‐Selandian age (ca. 63–59 Ma) in the Aertashi Formation. This is followed by the largest recorded proto‐Paratethys Sea incursion with a transgression estimated as early Thanetian (ca. 59–57 Ma) and a regression within the Ypresian (ca. 53–52 Ma), both within the Qimugen Formation. The transgression of the next incursion in the Kalatar and Wulagen formations is now constrained as early Lutetian (ca. 47–46 Ma), whereas its regression in the Bashibulake Formation is constrained as late Lutetian (ca. 41 Ma) and is associated with a drastic increase in both tectonic subsidence and basin infilling. The age of the final and least pronounced sea incursion restricted to the westernmost margin of the Tarim Basin is assigned as Bartonian–Priabonian (ca. 39.7–36.7 Ma). We interpret the long‐term westward retreat of the proto‐Paratethys Sea starting at ca. 41 Ma to be associated with far‐field tectonic effects of the Indo‐Asia collision and Pamir/Tibetan plateau uplift. Short‐term eustatic sea level transgressions are superimposed on this long‐term regression and seem coeval with the transgression events in the other northern Peri‐Tethyan sedimentary provinces for the 1st and 2nd sea incursions. However, the 3rd sea incursion is interpreted as related to tectonism. The transgressive and regressive intervals of the proto‐Paratethys Sea correlate well with the reported humid and arid phases, respectively in the Qaidam and Xining basins, thus demonstrating the role of the proto‐Paratethys Sea as an important moisture source for the Asian interior and its regression as a contributor to Asian aridification.  相似文献   

应用最小二乘法建立钾长石释光测年标准生长曲线     

杨宏宇  赵晖  王兴繁 《中国沙漠》2019,39(1):97-104

标准生长曲线（Standardised Growth Curve，SGC）法的提出为高效快速地测定释光样品的等效剂量（D_e）值提供了可能。不同实验室的放射源剂量率、操作流程、仪器误差等的不同会导致SGC参数的不同。运用最小二乘法标准化实验剂量校正后的信号L_ri/T_ri*D_e得到一条本实验室的标准生长曲线，用来快速得到等效剂量值。通过R软件实现了最小二乘法标准化过程，建立了50、100、150、200、250℃激发温度下的钾长石的标准生长曲线，分析发现250℃下的SGC收敛性最好，由于此温度下的信号衰退率可忽略不计，因此，我们用250℃激发温度下的SGC方程来估计样品的等效剂量。比较250℃ SGC D_e和250℃ MET-pIRIR D_e的一致性，发现在0~500 Gy范围内用SGC法估计的D_e和MET-pIRIR法估计的D_e非常接近，表明了此范围内SGC法的可靠性，而在>600 Gy范围内出现较大差别。一方面，此范围内用于拟合SGC的数据点较少导致高剂量区域内拟合的方程参数不够准确；另一方面，600 Gy与SGC对应的饱和剂量水平值844.5 Gy已经接近，所以在>600 Gy区域测出的D_e很可能出现较大偏差。因此需在今后工作中逐步积累更多样品，完善SGC参数，使其也能胜任较老年龄样品。  相似文献   

Developing a comprehensive evaluation method for Interconnected River System Network assessment: A case study in Tangxun Lake group     

Yang  Wei  Zhang  Liping  Zhang  Yanjun  Li  Zongli  Xiao  Yi  Xia  Jun 《地理学报(英文版)》2019,29(3):389-405

Journal of Geographical Sciences - The Interconnected River System Network (IRSN) plays a crucial role in water resource allocation, water ecological restoration and water quality improvement. It...  相似文献   

张掖盆地地下水硝酸盐污染与人体健康风险评价     

盛丹睿  温小虎  冯起  武君  司建华  吴敏 《中国沙漠》2019,39(5):37-44

地下水是张掖盆地的重要水资源，其硝酸盐污染尚未得到足够重视。对张掖盆地2004、2015年地下水硝酸盐浓度进行了系统分析，并采用美国环境保护署（USEPA）推荐的健康风险评价模型评估了地下水硝酸盐的健康风险。结果表明：自2004年以来张掖盆地地下水硝酸盐污染日趋严重。2015年硝酸盐浓度最高已达到283.32 mg·L^-1，17.61%的采样点硝酸盐氮浓度超过GB5749-2006《生活饮用水卫生标准》中饮用地下水限量值（20 mg·L^-1）。研究区人群经皮肤接触途径摄入硝酸盐的健康风险在可接受水平，而饮水摄入硝酸盐的健康风险较高，总风险中饮水途径引起健康风险的贡献率占99.40%，远大于皮肤接触途径。儿童经饮水摄入和皮肤接触两种途径的健康风险均显著高于成人，分别为成人的1.544倍和1.039倍。32.39%的采样点地下水硝酸盐对儿童的健康风险超出了可接受水平，14.79%的采样点地下水硝酸盐对成人的健康风险不可接受。甘州区城区、临泽县北部边缘及高台县城区周围硝酸盐浓度最高，这些区域内所有人群都面临硝酸盐引发的高健康风险，其余区域硝酸盐引发的健康风险相对较低。  相似文献